The Chilean Altiplano

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Thanks to the funding provided by the CICYT commision in Spain we are currently working on lake sediments from the Chilean Altiplano. The group is constituted by the collaboration of our institute with people from the University of Barcelona (Dr. A. Sáez, Dr. J.J. Pueyo), the Earth Science Institute "Jaume Almera" (Dr. C. Taberner and Dr. S. Giralt) and the University of A Coruña (Dr. R. Bao). Most of our work has been done in the framework of the ANDESTER project, recently finished:

Project: ANDESTER (Origen de los solutos y evolución paleohidrológica en sistemas lacustres cuaternarios con influencia hidrotermal; Altiplano de los Andes Centrales).

Period: 28 Dec 2001 - 27 Dec 2004

Funding: CICYT, Ministerio de Ciencia y Tecnología, Spain

Principal Investigators: A. Sáez, B. L. Valero-Garcés, C. Taberner, J. J. Pueyo, R. Bao, S. Giralt, A. Moreno, P. González-Sampériz, C. Herrera.

Lago Chungará in November 2002 during the field expedition

During ANDESTER project, up to 15 sediment cores were recovered from Lago Chungará (Northernl Chile Altiplano) with the coring platform from the Limnological Research Center (University of Minnesota). In addition, two water sampling campaigns were carried out to perform geochemical analyses in the water samples. The sediment cores were opened and described following the protocols defined in the Limnological Research Center and sampled for many different studies, some them in progress: diatoms, pollen, ostracods, carbon content, mineralogy, stable isotopes, etc. Here you can see some pictures of the sampling procedures.

Sampling Chungará cores in the IPE laboratory

In addition, cores 10A and 11A were analysed by the XRF Core Scanner from the University of Bremen thanks to the Paleostudies programme, obtaining continous geochemical measurements that are very useful to discriminate the presence of volcanic an carbonate layers (see an example). Age model was constructed after several 14C and U/Th dates resulting in a continuous sequence since 13000 cal yr BP. Preliminary results are going to be presented in several international conferences (see conferences page):

1.- Abstract for the 2004 AGU Fall meeting, 13-17 December, San Francisco, USA

Blas Valero-Garcés, Ana Moreno, Penelope Gonzalez-Samperiz, Alberto Saez, Roger Oriol Gibert, Juan Jose Pueyo, Conxita Taberner, Santiago Giralt, Roberto Bao, Larry Edwards, Doug Schnurrenberger, Amy Myrbo, Mark Shapley, Cristian Herrera and Antje Schwalb. A Holocene record of hydrological fluctuations from Lago Chungara (Chilean Altiplano)

The Holocene records of moisture availability in the Central Andes and the Altiplano show contrasting and even opposite signals and time-transgressive millennial-scale climatic changes across the region. The available records also evidence a pronounced north-south regional heterogeneity, particularly between the Titicaca Basin and the Atacama Altiplano. A multiproxy study of a 13 kyr record of Lago Chungará (18° 15' S, 69° 10' W, 4520 m a.s.l. Chilean Altiplano) provides new data to solve some of the paleoclimate controversies as regional moisture availability patterns during the early and mid Holocene and the onset of ENSO modern conditions.
Lago Chungará originated after the emplacement of the Parinacota volcano debris avalanche that blocked the Chungará River prior to 13 cal. kyrs ago. A seismic survey and fifteen Kullenberg cores allowed a detailed 3-D reconstruction of the sedimentary sequence (8 m). The chronological model is based on 5 AMS 14C on bulk organic matter and 3 U/Th dates on authigenic carbonates and shells. To assess the typically large (and variable) reservoir effect, we dated modern sediments and waters, and constrained the model with time markers based on a 210Pb age model for the last 150 yrs, volcanic ashes of known age, and the U/Th dates. We performed high–resolution analyses by an X-ray fluorescence core scanner and magnetic, sedimentological, mineralogical, isotopic, and biological (pollen, diatoms and ostracods) analyses on selected cores. Statistical analyses helped to separate the volcanic from the climate signal as the key driving forces in the hydrological and sedimentological evolution of the lake. Three main units are identified over the pre- collapse substrate. The basal unit (13 - 7.2 cal. kyrs BP) is a finely laminated diatomite. Preliminary analyses suggest a dominant interannual frequency that could be related to ENSO activity. The middle unit (7.2 – 4.5 cal. kyrs BP) is banded and it comprises diatomites and some carbonate-rich layers. Increased volcanic activity after 6 cal kyrs BP and climate-driven hydrological changes seem to have been conducive to increase carbonate precipitation during this period. The upper unit (after 4.5 cal. kyrs BP) is banded to massive and it contains abundant volcanic layers (lapilli, ash layers). Seismic features identified in littoral areas and interpreted as evidence for lower lake level periods and a subsequent raise seem to correlate with the middle unit and the transition to the upper unit.
The reconstructed hydrological variability in the Lake Chungara shows fluctuating lake levels during the early Holocene (13 to 7.2 cal kyrs BP), and the mid Holocene (7.2 – 4.5 cal kyrs BP), and the highest lake levels during the late Holocene. The laminated basal unit suggests that ENSO-like variability was also present during the early Holocene in the Altiplano. The presence of mid – Holocene arid intervals supports the regional extent of this period of reduced moisture through the region.

2.- Abstract for the EGU General Assembly, 24-29 April, 2005, Vienna, Austria:

Moreno, A. (1); Giralt, S. (2); Valero-Garcés, B. L. (1); Sáez, A. (3); Bao, R. (4); Pueyo, J.J. (3); González-Sampériz, P. (1); Oriol, R. (3), Taberner, C. (2). Effects of climate, lake productivity and volcanic influences unraveled for last 13000 years in the Central Chilean Altiplano: a high-resolution geochemical study

(1) Pyrenean Institute of Ecology - CSIC, Apdo 202, 50080 Zaragoza, Spain, (2) Institute of Earth Sciences Jaume Almera - CSIC, Lluis Sole i Sabaris s/n, 08028 Barcelona, Spain, (3) Faculty of Geology, University of Barcelona, Marti i Franques s/n, 08028 Barcelona, Spain, (4) Universidade da Coruña, Facultade de Ciencias, Campus da Zapateira s/n, 15071 A Coruña, Spain

Available records from the Central Andes and the Altiplano evidence a pronounced heterogeneity in the regional moisture availability during the Holocene. The multiproxy study (seismic survey, high-resolution geochemical profiles carried out by a XRF Core Scanner, mineralogical composition, TIC, TOC, biogenic silica and diatoms) of the Lago Chungará sedimentary infill (18° 15' S, 69° 10' W, 4520 m a.s.l. Chilean Altiplano) has provided new insights which could contribute to solve some of the regional paleoclimate controversies, such as the Mid-Holocene aridity crisis or the onset of ENSO conditions.
A seismic survey and fifteen Kullenberg cores (up to 8 m long) allowed a detailed 3-D reconstruction of the sedimentary architecture. The chronological framework of the cores was established using 13 radiocarbon and 4 238U/230Th dates, allowing to reconstruct the lacustrine evolution for the last 13,000 cal years BP. Three main sediment sources were distinguished along the record: volcanic supply from the nearby volcanoes (represented by Fe, Ti, K and % of plagioclase), endogenic carbonate production (highlighted by the Ca/Ti, Sr/Ti, % calcite and TIC variations) and bioclastic remains, mainly diatoms (Si/Ti, biogenic opal, S/Ti, %TOC).
Three main units were identified over the pre-collapse substrate:
1.- The basal unit (13 - 7.2 cal. kyrs BP) is a finely laminated diatomite. Preliminary analyses suggest a dominant interannual frequency that could be related to the ENSO activity. Furthermore, our records indicate an increase in productivity during the Early Holocene, coherent with the raise of paleotemperatures in the nearby Sajama ice core.
2.- The middle unit (7.2 – 4.5 cal. kyrs BP) is banded and it comprises diatomites and some carbonate-rich layers. Increased volcanic activity after 6 cal kyrs BP and climate-driven hydrological changes seemed to be the main promoters of the carbonate precipitation that occurred during this period. An arid Mid-Holocene is recorded in the Lago Chungará sediments supporting the regional low moisture availability of this period.
3.- The upper unit (after 4.5 cal. kyrs BP) is banded to massive and it contains abundant volcanic layers (lapilli, ash layers). A high correlation between the volcanic input in Lago Chungará and the total particles coarser than 63 µm recorded in the Sajama ice core is evident for the last 6000 years.
The high-resolution attained in this study allowed us to identify several sharp and abrupt episodes of climate change during the Holocene, such as those observed during the Mid-Holocene (among 7.5 and 5.5 kyrs) and the 8.2 kyrs event. Timing of these events and their potential climatic forcings are discussed in comparison with adjacent records, such as those from Lake Titicaca.

3.- Abstract for the Conference on the El Niño phenomenon and its global impact, 16-20 May, 2005 Guayaquil, Ecuador:
S. Giralt (1), A. Moreno (2), B. Valero (2), A. Saez (3), R. Bao (4), C. Taberner (1), J.J. Pueyo (5), P. Gonzalez (2), C. Herrera (6), The sedimentary record of Lago Chungara (Chilean Altiplano): a high resolution archive of the ENSO phenomenon during the late Glacial and Early Holocene

(1) Institute of Earth Sciences 'Jaume Almera' (CSIC), Lluis Sole i Sabaris s/n, E-08028 Barcelona (Spain), sgiralt@ija.csic.es
(2) Institute of Pyrenean Ecology (CSIC), Apdo 202, E-50080 Zaragoza (Spain)
(3) Dept. of Stratigraphy, Paleontology and Marine Geosciences, Faculty of Geology, University of Barcelona, Marti i Franques s/n, E-08028 Barcelona (Spain)
(4) Faculty of Sciences, University of A Coruña, Campus da Zapateira s/n, E-15071 A Coruña (Spain)
(5) Dept. of Geochemistry, Faculty of Geology, University of Barcelona, Marti i Franques s/n, E-08028 Barcelona (Spain)
(6) Dept. of Geological Sciences, University 'Catolica del Norte', Avda. Angamos, 060010 - Casilla 1280, Antofagasta (Chile)

The Central Andes and the Altiplano has provided exceptional records of climate variability of the last millenia, but little is known about the mechanisms and processes that have triggered such variability. A high-resolution multiproxy study of the sedimentary record of Lago Chungara (18°15'S, 69°10'W, 4520 m a.s.l., Chile an Altiplano) provides new data to solve some of the paleoclimate controversies as regional moisture availability patterns during the Late Glacial and Early Holocene and the onset of ENSO modern conditions.
A seismic survey and fifteen Kullenberg cores (8 m long) allowed a detailed 3-D reconstruction of the sedimentary sequence as well as to define the major hydrological and climatic episodes. The recovered sedimentary sequences show three main units. The basal unit is minly composed by rhythms and cycles of different lamina constituted by diatomaceous ooze with carbonates and organic matter. The middle unit is banded and it comprises diatomites, volcanoclastic and carbonate-rich layers. The upper unit is banded to massive and it contains abundant volcanoclastic layers (ashes/ignimbrites).
X-ray fluorescence core scanner every 2 mm and magnetic, sedimentological, mineralogical, isotopic, gray curve (one sample every 0.1 mm) and biological (pollen, diatoms and ostracods) analyses were performed on two selected cores (Core 10 and 11) in order to characterize the environmental evolution of the lake. The chronological model of these sedimentary sequences is based on 5 AMS 14C and 3 238U/230Th.
Statistical analyses (cluster and detrended correspondence (DCA) analyses) were employed to separate the volcanic from the climate signal, as the key driving forces in the hydrological and sedimentological evolution of the lake. The volcanic signal appeared in the first eigenvector of the analyses whereas the climatic signal was reconstructed from the segon eigenvector of the DCA. The climatic signal seems to be related with the productivity oscillations of the lake. Spectral analyses (Fast Fourier Transformation (FFT) and Time Frequency (TF) analyses) were performed in order to characterize the temporal evolution of the climate signal.
Here we will present the results of the basal laminated unit. According to the chronological framework this unit comprises the Late Glacial - Holocene transition (approx. 12,800 - 9,800 calendar radiocarbon years).
The FFT analyses of the climate signal obtained from the DCA for the basal laminated unit highlight the presence of cyclicity of 35 - 51 years, which could be interpreted as the solar Bruckner cycle as well as interdecadal changes in the variance of the ENSO phenomenon. The FFT analyses results carried out on the gray curve also reinforce the hypothesis of the solar control of the productivity of the lake (due to the presence of the 11-years Schwalbe, the 22 - 23-years Hale, the 35-years Bruckner and the approx. 90-years Gleissberg cycles), as well as the presence of strong to very strong ENSO phenomenon (8.2 and 7.5-years cycles). The TF analyses developed on the gray curve suggest that the solar activity and the ENSO phenomenon were not always active during the same period of time.

"Future" work in the Chilean Altiplano

Recently, we have started with a new project funded by the CICYT (Ministerio de Educación y Ciencia, Spain) called LAVOLTER:

Project: LAVOLTER (Fenómenos extremos en el registro sedimentario de lagos en contexto volcánico-hidrotermal activo).

Period: 13 Dec 2004 - 13 Dec 2007

Funding: CICYT, Ministerio de Ciencia y Tecnología, Spain

Principal Investigators: C. Taberner, A. Sáez, B. L. Valero-Garcés, J. J. Pueyo, R. Bao, S. Giralt, A. Moreno, P. González-Sampériz, C. Herrera.

In the framework of this project we will address the study of several Quaternary lake records in the Pacific area, 1) with different degrees of geothermal control and 2) under the influence of the El Niño Southern Oscillation. The objective is the discrimination and evaluation of climatic signatures versus those related to volcanic and geothermal activity in the area. Two lakes with different geothermal activity have been selected in the Altiplano of Northern Chile (Chungará and Surire). The three lakes of the Eastern Island have been chosen for the lack of thermal springs and for their location with respect to the El Niño Southern Oscillation. This proposal has developed as a natural follow up of the previos ANDESTER project. Main objectives of LAVOLTER project are: 1) differentiation of climatic signatures in a hydrothermal-volcanic context, from those strictly climatic, in lacustrine sediments; and 2) calibration and evaluation of the signatures recorded in the selected lake records, based upon the variability of the sedimentary record in the same lake system and the recorded variability between the selected lake systems. The isolation of the strictly climatic signatures from those related to other processes in lake records is of extreme interest in the interpretation of the past climatic variability and its use as a predictive tool of climatic variability derived of the Global Climate Change. Results of this project will enable the differentiation and isolation of climatic signatures from signatures related to local perturbations, mainly related to geothermal processes.

Previous work in the Chilean Altiplano

Our work in South America started almost ten years ago from our collaboration with the University of Bern (Switzerland), and the Limnological Research Center (University of Minnesota, USA) in the study of lakes in the Chilean Altiplano. The collaboration with the Departments of Archaeology of the University of Buenos Aires and the Universidad Nacional de Catamarca has helped to span our activities to the Argentinian Altiplano. Several lacustrine records from high altitude Chilean and Argentinian lakes have shown a strong signature of the Little Ice Age in the Altiplano. Besides, many records indicate a large effective moisture variability at decadal scale.

Projects: Climate Change in the Arid Andes:

Period: 1993-1996

Funding: National Swiss Foundation

Principal Investigators: Bruno Messerli & Martin Grosjean (University of Bern, Department of Physical Geography).

Sites: Laguna Chungará, Laguna Miscanti, Laguna del Negro Francisco

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Bibliography:

General references:

Valero-Garcés, B.L., Grosjean, M., Schwalb, A.,Schreir, H., Kelts, K., & Messerli, B., 2000. Late Quaternary lacustrine deposition in the Chilean Altiplano (18 ° - 28 ° S). En: Gierlowski - Kordech, E., & Kelts, K. (eds), Global Geological Record of lake Basins. Volume 2, AAPG. (in press).

Valero-Garcés, B.L., Grosjean, M.,Schreier, H., Kelts, K., & Messerli, B., 1999. Holocene lacustrine deposition in the Atacama Altiplano: facies models, climate and tectonic forcing. Palaeogeography, Palaeoclimatology, Palaeoecology 151(1-3):101-125.

ABSTRACT. We investigate the Holocene sedimentary infilling of two high altitude (> 4000 m a.s.l.) lacustrine basins in the subtropical regions of the Atacama Altiplano (Central Andes, northern Chile) that today contain permanent, shallow saline lakes: Laguna del Negro Francisco (27° S) and Laguna Miscanti (23°S). Laguna Miscanti was surveyed with multifrequency, high resolution seismic techniques and sediment cores were retrieved from off-shore areas of both lakes. Because of the geological location of these lacustrine basins within the active Andean convergent margin, and the presence of present and past climatic gradients in the Altiplano, our detailed sedimentologic, mineralogic and geochemical study evaluates tectonic, volcanic, and climatic controls on lacustrine sedimentation in an arid environment.

Both lakes originated by tectonic and volcanic activity during the Pleistocene. Tectonic control of basin dynamics was clearly exerted during the early stages: increased subsidence was responsible for alluvial fan activity in the Laguna Miscanti basin prior to the establishment of the lake, and the Negro Francisco basin changed from exhoreic to endorheic. Hydrogeologic conditions needed to maintain the two perennial saline lakes are largely controlled by the basins' tectonic history.

The evolution of Laguna del Negro Francisco comprises four successive stages: perennial saline carbonate - sulfate lake; saline pan - saline lake complex with a carbonate - sulfate brine; a perennial brackish stage with high macrophyte (Chara) productivity and mostly calcite formation, and a residual stage with halite precipitation. The depositional history recorded in the Miscanti core illustrates the evolution from an aragonite-producing, ephemeral saline lake to a macrophyte-dominated perennial brackish lake, with an aragonite saline pan - saline lake complex and a calcite-producing perennial brackish lake as intermediate stages.

The hydrologic budget of the lakes is a direct response to effective moisture (precipitation - evaporation) fluctuations and, therefore, climate variability has played a major role in chemical composition and lake level changes. Climate forcing has controlled the depositional history of the lakes during the Holocene. Our study illustrates different responses of lake systems to external climatic forcing, especially with respect to cyclicity, threshold dynamics and the importance of sedimentary recycling. The main sedimentary sequences in both lakes correspond to cycles of increasing and decreasing effective moisture. However, this cyclicity is characterized by abrupt change rather than gradual evolution. Threshold dynamics modulated limnogeological changes and caused a stepwise evolution of the lacustrine systems. Laguna Miscanti and Laguna del Negro Francisco sedimentary sequences provide depositional models for small, topographically closed, brackish to saline lakes that developed on active margins and evolved under fluctuating but generally arid climatic conditions.

Laguna del Negro Francisco

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Grosjean, M., Valero-Garcés, B., Geyh, M.A., Messerli, B., Schreier H., & Kelts, K.,1997. Mid and Late Holocene Limnogeology of Laguna del Negro Francisco, northern Chile and its paleoclimatic implications.The Holocene 7(2): 151-159

ABSTRACT. Lacustrine sediments from the high elevation, endorheic, saline lake Negro Francisco (27º 28’ S / 69º 14’ W, 4125 m) provide a detailed mid- and late Holocene environmental history of the southern Chilean Altiplano. Mineralogy, chemical composition and sedimentary facies analyses of the deposits confirm the regional significance of mid-Holocene aridity betweeen 6000 and 3800 BP. Precipitation rates were significantly lower than the c. 250 mm yr-1 of today. Fully arid conditions were interrupted by short term moist spells with an average return period of about 200 years. Effective moisture increased after 3800 BP and peaked between 3000 and 2600 BP and between 2200 and 1800 BP in two phases with conditions more humid than today. Comparison with the regional palaeodata suggest that these two late-Holocene humid spells were most likely related to Pacific moisture sources. Salinity levels increased again in Laguna del Negro Francisco after 1800 BP. The onset of modern climatic conditions was a stepwise, nonlinear process. However, the functioning of modern climate in this remote part of the world is not understood well enough to explain fully possible mechanisms of climatic changes in the past.

Figure. The Laguna del Negro Francisco Record.

Laguna Miscanti

Valero-Garcés, B.L., Grosjean, M., Schwalb, A., Geyh, M., Messerli, B. & Kelts, K.,1996. Limnogeology of Laguna Miscanti: evidence for mid to late Holocene moisture changes in the Atacama Altiplano (northern Chile). Journal of Paleolimnology. 16: 1-21.

ABSTRACT. Sedimentological, mineralogical and geochemical analyses of sediment cores from 9 m-deep, saline, Laguna Miscanti, Chile (23° 44'S, 67°46'W, 4140 m a.s.l.) together with high-resolution seismic profiles provide a mid to late Holocene time series of regional environmental change in the Atacama Altiplano constrained by 210Pb and conventional 14C dating. The mid Holocene was the most arid interval since the last glacial maximum, as documented by subaerial exposure and formation of hardgrounds on a playa surface. Extremely low lake levels during the mid Holocene appear consistent with lower effective moisture recorded at other sites along the Altiplano and in the Amazon Basin. Termination of this arid period represented a major shift in the regional environmental dynamics and inaugurated modern atmospheric conditions. The cores show a progressive upward increase in effective moisture interrupted by numerous century-scale drier periods of various intensities and durations that characterize a fluctuating late Holocene climate. In spite of chronological uncertainties, the major environmental changes seem to correlate well with the available paleorecords from the region providing a coherent account of effective moisture variability in the tropical highlands of South America.

Figure. The Laguna Miscanti Record.

Figure. The Miscanti evidence for mid-Holocene maximum aridity

Laguna Chungará.

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Foto by Antje Schwalb

Valero-Garcés B.L. & Delgado-Huertas, A., 1999. Carbon Isotopic signatures in Laguna Chungará, Chile: a lake productivity record since the Little Ice Age. The 2nd International Congress of Limnogeology, (Brest, France), Abstract Book, pp. 74.

ABSTRACT. Laguna Chungará (18° 15' S, 69° 10' W, 4520 m a.s.l. ) stretches along the Chilean-Bolivian border at the northeastern edge of the Lauca Basin, the westernmost and highest fluvio-lacustrine basin in the Andean Altiplano. Laguna Chungará lies in a tectonic basin, with a maximum water depth of 40 m, a surface area of 21.5 km2, and a volume of about 385 million m3. The main inlet is the Chungará River (300 to 500 l/s). There is no surface outlet, and groundwater outflow has been estimated as about 6 x106 m3/yr. Evaporation (1200 mm/yr) greatly exceeds annual rainfall (440 mm/y). The lake is polymictic, oligotrophic, contains 1.2 g/l TDS and water chemistry is of Na- Mg - HCO3 - SO4 type and alkaline (pH=9).The phytoplankton community possesses few species, and diatoms are scarce. Macrophyte communities in the littoral zone form dense patches. The fauna includes endemic cyprinodontid fish genera (e.g. 19 species of Orestias).

The sediment sequence of Laguna Chungara is composed of two lacustrine depositional units that overlie the massive volcanic substrate in the smaller, shallower eastern subbasin (sediment thickness up to 5 m) and also in the main, deeper, NW-SE trending basin (sediment thickness about 10 m). An older seismic unit, with less well-defined reflectors, and interpreted as fluvial-lacustrine, occurs in the northwestern basin. The sediments in the littoral platform of the eastern subbasin encompass three different subenvironmens (Characeae-dominated lacustrine shelf, macrophyte-dominated littoral, and peat bog). The lake level fluctuations reflect century- to millenium-scale oscillations in the hydrological history of the basin.

A century to decadal resolution record of paleolimnological change during the last centuries was obtained from a short core (55 cm long) retrieved from the off-shore areas (20 m water depth). Modern pelagial sediments are black, organic-rich (up to 25 %) laminated muds with relatively low carbonate content (6-8%). Discrete mm-thick white laminae occur at some intervals, and are mainly composed of calcite (up to 50 %). The core was sampled in the field at 0.5 cm intervals, and analyzed in the lab for sediment composition, mineralogy, and stable isotopes. Oxygen and carbon isotopic compositions of carbonate (calcite), and d 13C values of organic matter were measured on bulk-sediment samples following standard procedures. 210Pb dating was performed using the Constant Rate of Supply (CRS) model.

The basal sediment from the short core (55- 26 cm) show low carbonate and relatively high but fluctuating organic matter content. There is a negative correlation between organic matter content and carbon isotope values, and the d 13C o.m. values display an increasing trend. According with the 210Pb chronology these sediments were deposited during the Little Ice Age (LIA). An interval with white laminae composed of calcite (26-20 cm) corresponds to a sharp positive excursion in both d 13C o.m. and d 13C calcite. This abrupt change could correspond to the end of the LIA, and would correlate with the abrupt termination of the LIA recorded in the Quelcaya ice cap. Lower d 13C o.m. values during the beginning of the XX century are followed by a sharp negative shift in d 13C o.m., and d 13C calcite corresponding to the ocurrence of another calcite-rich interval deposited during the 1930-1950s. Finally, increasing d 13C o.m. values in the upper 10 cm correspond with decreasing d 13C calcite.

Sediment composition and carbon isotopic ratios of bulk organic matter and calcite provide paleolimnological information, as organic matter origin, lake paleoproductivity, and paleohydrology. Changes in the d 13C of authigenic lacustrine carbonate and lacustrine organic matter reflect variations in the dissolved inorganic carbon (DIC) pool, controlled by input and biological processes, mainly respiration and photosynthesis. Increased photosynthesis produces a relative enriched d 13C o.m. and d 13C calcite due to productivity-driven enrichement in DIC; increasing contribution of 12C-rich CO2 results in depleted d 13C values. The isotopic signatures suggest that peaks in calcite production are associated with distinctive periods of increased organic productivity. The fluctuations in Laguna Chungara carbon budget seem to reflect changes in lacustrine productivity driven by paleoenvironmental and paleoclimatic changes during the last centuries.

Figure. The Laguna Chungará record.

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